Full-Scale Removal of Arsenate and Chromate from Water Using a Limestone and Ochreous Sludge Mixture as a Low-Cost Sorbent Material
Abstract:The oxyanions arsenate (AsO4 3−) and chromate (CrO4 2−) are major freshwater contaminants. Arsenate is a problematic contaminant in drinking water reservoirs, and chromate limits the use of urban stormwater runoff. High-capacity, low-cost, energy-efficient treatment technologies are required for the removal of these toxic anions from freshwater sources. Using a 50-m-long dual porosity filter, with limestone as filtering grains, treating stormwater runoff from Copenhagen, Denmark, we tested if addition of the waste product ochreous sludge can improve the removal of arsenate (As) and chromate (Cr) without compromising the calcite's removal affinity towards metallic cations. Upon on-site embedding of the ochreous sludge, removal of arsenic and chromium was improved greatly, and copper (Cu) removal remained high. Steady-state effluent concentrations were reduced from 31 to 2 µg As/L, 127 to 1.5 µg Cr/L, and 18 to 9.6 µg Cu/L upon mixing with the ochreous sludge. Limestone-ochreous sludge represents a promising low-cost oxyanion and cation sorbent operating at neutral pH without pH control.
Document Type: Research Article
Publication date: May 1, 2010
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- Water Environment Research® (WER®) publishes peer-reviewed research papers, research notes, state-of-the-art and critical reviews on original, fundamental and applied research in all scientific and technical areas related to water quality, pollution control, and management. An annual Literature Review provides a review of published books and articles on water quality topics from the previous year. Published as: Sewage Works Journal, 1928 - 1949; Sewage and Industrial Wastes, 1950 - 1959; Journal Water Pollution Control Federation, 1959 - Oct 1989; Research Journal Water Pollution Control Federation, Nov 1989 - 1991; Water Environment Research, 1992 - present.
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