Metal Ion Uptake from Aqueous Solution by Olive Stones: A Carbon-13 Solid-State Nuclear Magnetic Resonance and Potentiometric Study
Authors: Nurchi, Valeria Marina; Floris, Costantino; Pinna, Rosalba; Fiol, Núria; Villaescusa, Isabel
Source: Water Environment Research, Volume 79, Number 11, October 2007 , pp. 2363-2367(5)
Publisher: Water Environment Federation
Abstract:
The use of biomasses that result from the agriculture and food industries in removing heavy metals from wastewaters is attracting increasing interest. We present a joined potentiometric and cross polarization magic angle spinning (CP-MAS) carbon-13 ( 13C) nuclear magnetic resonance (NMR) study on the interaction of olive stones with copper(II), nickel(II), and cadmium(II). The potentiometric measurements allow both to distinguish two kind of basic sites in the olive stones and to postulate the coordination models for the three studied metals. The NMR spectral analysis allows the attribution of the different signals to the components of the olive stone matrix. A comparison of CP-MAS 13C NMR spectra of the samples after metal treatment suggests a specific complexation between metal ions and hydroxyl groups on guaiacyl and syringyl moieties.Keywords: olive stones; solid-state cross polarization magic angle spinnin; heavy metals; cadmium; copper; nickel; potentiometric titration; metal uptake
Document Type: Research article
DOI: http://dx.doi.org/10.2175/106143007X183880
Publication date: 2007-10-01
- Water Environment Research® (WER®) publishes peer-reviewed research papers, research notes, state-of-the-art and critical reviews on original, fundamental and applied research in all scientific and technical areas related to water quality, pollution control, and management. An annual Literature Review provides a review of published books and articles on water quality topics from the previous year. Published as: Sewage Works Journal, 1928 - 1949; Sewage and Industrial Wastes, 1950 - 1959; Journal Water Pollution Control Federation, 1959 - Oct 1989; Research Journal Water Pollution Control Federation, Nov 1989 - 1991; Water Environment Research, 1992 - present.
- Editorial Board
- Information for Authors
- Submit a Paper
- Subscribe to this Title
- Membership Information
- Information for Advertisers
- WEF Bookstore
- ingentaconnect is not responsible for the content or availability of external websites
- In this: publication
- By this: publisher
- In this Subject: Earth and Environmental Sciences , General & Civil Engineering , Hydraulic & Environmental Engineering
- By this author: Nurchi, Valeria Marina ; Floris, Costantino ; Pinna, Rosalba ; Fiol, Núria ; Villaescusa, Isabel

Shopping cart
Receive new issue alert
Get Permissions