Use of Natural Clinoptilolite to Improve Water Quality: Sorption and Selectivity Studies of Lead(II), Copper(II), Zinc(II), and Nickel(II)

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Abstract:

Natural clinoptilolite can be used as an ion exchanger for removal of heavy metals and treatment of environmental pollution because of its desirable characteristics of high ion exchange selectivity and resistance to different media.



In this work, the potential of natural clinoptilolite from Gördes mines (West Anatolia, Turkey) for the uptake of lead(II), nickel(II), copper(II), and zinc(II), from their single and mixed ion solutions, was evaluated using the batch method. The mineralogical and chemical properties of the sorption material were carried out by X-ray diffraction, X-ray fluoremetry, scanning electron microscopy, and wet analysis.



Contact time, initial solution pH, solid-to-liquid ratio, and initial metal cation concentration were determined as single ion sorption parameters. The silicon/aluminum ratio and the theoretical and equivalent exchange capacities, both in single and mixed solutions, were established. Corresponding adsorption constants and distribution coefficients have been found.

Keywords: cation exchange; cation selectivity; clinoptilolite; heavy metal sorption

Document Type: Research Article

DOI: http://dx.doi.org/10.2175/106143006X111880

Publication date: March 1, 2007

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  • Water Environment Research® (WER®) publishes peer-reviewed research papers, research notes, state-of-the-art and critical reviews on original, fundamental and applied research in all scientific and technical areas related to water quality, pollution control, and management. An annual Literature Review provides a review of published books and articles on water quality topics from the previous year.

    Published as: Sewage Works Journal, 1928 - 1949; Sewage and Industrial Wastes, 1950 - 1959; Journal Water Pollution Control Federation, 1959 - Oct 1989; Research Journal Water Pollution Control Federation, Nov 1989 - 1991; Water Environment Research, 1992 - present.
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