Enhanced Biodegradation of Azo Dyes Using an Integrated Elemental Iron-Activated Sludge System: II. Effects of Physical–Chemical Parameters
As part of a study to evaluate an integrated zero-valent iron (Fe0)-biological oxidation process for treating azo dye wastewaters, we conducted batch and column experiments with the azo dye orange G to assess the effects of solution conditions on the performance of iron pretreatment. The influence of iron type and surface area, solution pH, dissolved inorganic salts, and phosphate ion on the reduction (decolorization) of orange G solution were examined. In batch experiments, increased iron surface area, decreased pH, and chloride and sulfate salts enhanced dye decolorization, whereas high pH (9.9) and phosphate concentrations (>3 mg/L PO4-P) inhibited dye reduction. Results from batch experiments were confirmed in column experiments. An increase in temperature from 22 to 35°C resulted in a near doubling of the reduction rate constant in a column study. The abiotic reduction results illustrate the feasibility and potential limitations of an integrated iron column, activated sludge treatment process for wastewaters containing azo dyes.
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Document Type: Research Article
Publication date: 2006-01-01
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Water Environment Research (WER) publishes peer-reviewed research papers, research notes, state-of-the-art and critical reviews on original, fundamental and applied research in all scientific and technical areas related to water quality, pollution control, and management. An annual Literature Review provides a review of published books and articles on water quality topics from the previous year. Published as: Sewage Works Journal, 1928 - 1949; Sewage and Industrial Wastes, 1950 - 1959; Journal Water Pollution Control Federation, 1959 - Oct 1989; Research Journal Water Pollution Control Federation, Nov 1989 - 1991; Water Environment Research, 1992 - present.
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