Removal of Selenite and Chromate Using Iron(III)-Doped Alginate Gels

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Abstract:

Oxyanionic contaminants, specifically selenium and chromium(VI), were removed from solution by sorption onto gel beads formed by pretreating the biopolymer alginic acid with calcium and iron(III). The calcium-iron gel beads were found to be effective at removing selenium(IV) from solution. Chromium(VI) removal was less effective and the rate of sorption was slower than that of selenium(IV). At an initial selenium(IV) concentration of 400 μg/L (5.1 μM), up to approximately 94% removal of selenium from solution was achieved by a 120-hour equilibration with 20 calcium-iron beads (10 mg/L or 180 μM total iron). Optimal selenium(IV) removal and stability of the calcium-iron beads were achieved at pH 4. Selenium(IV) sorption and kinetics data were comparable with those observed previously for arsenic(V). Selenium(IV) sorption data, as a function of dissolved concentration and iron content, were modeled. As calcium-iron beads became saturated, the extent of sorption of selenium(IV) or arsenic(V) was decreased by the presence of competing contaminant oxyanions or nonhazardous inorganic anions such as phosphate.

Keywords: ALGINATE; BIOPOLYMER; CHROMATE; GEL BEAD; IRON(III)-DOPED; OXYANION; REMOVAL; SELENITE; WASTEWATER

Document Type: Research Article

DOI: http://dx.doi.org/10.2175/106143098X121950

Publication date: March 1, 1999

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  • Water Environment Research® (WER®) publishes peer-reviewed research papers, research notes, state-of-the-art and critical reviews on original, fundamental and applied research in all scientific and technical areas related to water quality, pollution control, and management. An annual Literature Review provides a review of published books and articles on water quality topics from the previous year.

    Published as: Sewage Works Journal, 1928 - 1949; Sewage and Industrial Wastes, 1950 - 1959; Journal Water Pollution Control Federation, 1959 - Oct 1989; Research Journal Water Pollution Control Federation, Nov 1989 - 1991; Water Environment Research, 1992 - present.
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