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Feasibility, system design, and economic evaluation of radiolytic degradation of 2,3,7,8-tetrachlorodibenzo-p-dioxin on soil

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This research shows that gamma irradiation is both a technically and economically feasible method to degrade chlorinated dioxins on soil. Approximately 99% degradation of dioxin on a model soil was achieved using gamma radiation at a dose of 800 kGy. In addition, this research determined the initial pathway of destruction, identified several controlling parameters, and developed a mass balance on degradation. The general applicability of this model behavior was successfully tested in a native contaminated soil where nearly 75% of the dioxin was destroyed at a dose of 450 kGy. Through a theoretical and conceptual understanding of radiolysis in soil, a sound basis for engineering design was established. Gamma radiation sources are commercially available, and this research outlines a new application of an established technology. A number of irradiator designs are proposed, and preliminary economic estimates are made to demonstrate that radiolysis can be a real alternative to incineration.
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Document Type: Research Article

Publication date: 1996-03-01

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  • Water Environment Research (WER) is published monthly, including an annual Literature Review. A subscription to WER includes access to the latest content back to 1992, as well as access to fast track articles. An individual subscription is valid for 12 months from month of purchase.

    Water Environment Research (WER) publishes peer-reviewed research papers, research notes, state-of-the-art and critical reviews on original, fundamental and applied research in all scientific and technical areas related to water quality, pollution control, and management. An annual Literature Review provides a review of published books and articles on water quality topics from the previous year.

    Published as: Sewage Works Journal, 1928 - 1949; Sewage and Industrial Wastes, 1950 - 1959; Journal Water Pollution Control Federation, 1959 - Oct 1989; Research Journal Water Pollution Control Federation, Nov 1989 - 1991; Water Environment Research, 1992 - present.
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