The Importance of Slow Kinetic Reactions in Simultaneous Chemical P Removal
Laboratory and full-scale experiments were performed in order to investigate the effect of mixing, as represented by the mean velocity gradient, G-value (Grady et al, 1999), and time dynamics in chemical phosphorus removal. The results prove that the chemical reactions occurring during phosphorus removal upon addition of trivalent metal salts (Fe, Al) cannot be described with the currently applied equilibrium theory (WEF, 1998). Two reactions are postulated: a) a significant part of the phosphate, depending on the applied G, is removed instantaneously, or within the first few minutes. This fast reaction however is not a simple equilibrium precipitation, since it involves varying stoichiometry and varying residual concentrations; b) a smaller part of the total initial phosphate is removed by a slow kinetic reaction (termed adsorption). The time constant of this reaction is in the order of hours to days. Pure metal hydroxide flocs, formed without the presence of phosphate, also remove phosphorus kinetically. The role of this reaction is more expressed in plants where mixing at dosage point is inadequate, particularly during simultaneous phosphorus removal. The slow reaction has increased relevance when residual phosphate concentrations are in a very low range, below 0.1 – 0.2 mgP/L, a range that is an increasingly common permitted requirement for wastewater treatment facilities. Thus, the slow reaction can be used with advantage to achieve very low phosphorus residuals via simultaneous precipitation. Additionally, this reaction may be important for tertiary blanket clarifiers and for tertiary clarifiers with internal sludge recirculation.
No Reference information available - sign in for access.
No Citation information available - sign in for access.
No Supplementary Data.
Document Type: Research Article
Publication date: 2006-01-01
More about this publication?
- Proceedings of the Water Environment Federation is an archive of papers published in the proceedings of the annual Water Environment Federation® Technical Exhibition and Conference (WEFTEC® ) and specialty conferences held since the year 2000. These proceedings are not peer reviewed. A subscription to the Proceedings of the Water Environment Federation includes access to most papers presented at the annual WEF Technical Exhibition and Conference (WEFTEC) and other conferences held since 2000. Subscription access begins 12 months after the event and is valid for 12 months from month of purchase. A subscription to the Proceedings of the Water Environment Federation is included in Water Environment Federation (WEF) membership.
WEF Members: Sign in (right panel) with your IngentaConnect user name and password to receive complimentary access. Access begins 12 months after the conference or event
- Subscribe to this Title
- Membership Information
- About WEF Proceedings
- WEFTEC Conference Information
- Learn about the many other WEF member benefits and join today
- Ingenta Connect is not responsible for the content or availability of external websites