Direct synthesis of dimethyl ether from synthesis gas over metal-pillared ilerites

Authors: Ahn, Sung-Hwan¹; Kim, Song-Hyoung¹; Hahm, Hyun-Sik¹

Source: Research on Chemical Intermediates, Volume 34, Numbers 8-9, 2008 , pp. 793-801(9)

Publisher: VSP, an imprint of Brill

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Abstract:

The capability of metal (Cu, Zn)-pillared ilerites and metal oxide (CuO, ZnO)-impregnated metal-pillared ilerites for direct synthesis of dimethyl ether (DME) from synthesis gas was explored. The metal-pillared ilerites were synthesized and characterized by XRD, BET, ICP-AES and SEM. The reaction was carried out in a fixed bed reactor with the prepared catalysts at different temperatures (200, 250, 300°C), 20 bar and H₂/CO ratio of 2. For CuO/Zn-ilerite catalyst, CO conversion was about 62% and selectivity to DME was about 89% at 250°C.

Keywords: ILERITE; DIMETHYL ETHER (DME); DME DIRECT SYNTHESIS; SYNTHESIS GAS

Document Type: Research article

DOI: 10.1163/156856708786189320

Affiliations: 1: Department of Chemical Engineering, Myongji University, San 38-2, Namdong, Yongin, Gyeonggi-do 449-728, South Korea

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