AB monomers: II, synthesis and polymerization of AB monomers containing citracon- or maleimide and allylphenyl groups

Authors: Gaina, V.; Gaina, C.

Source: Designed Monomers & Polymers, Volume 10, Number 1, 2007 , pp. 91-104(14)

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Abstract:

New bifunctional AB monomers containing citracon- or maleimide and allylphenyl groups were synthesized by the condensation reaction of maleimidobenzoic acid chloride or citraconimidobenzoic acid chloride with eugenol or allylphenol. The structures of the monomers were confirmed by IR, ¹H-NMR and ¹³C-NMR spectroscopy. Using the ene-addition reaction and Diels-Alder polymerization new polyesters were prepared. Thermal curing behavior of monomers was investigated by DSC analysis. All polymers were characterized by IR spectral studies and thermogravimetric analysis.

Keywords: MALEIMIDE; ALLYLMALEIMIDE; ENE-REACTION

Document Type: Research article

DOI: http://dx.doi.org/10.1163/156855507779763621

Affiliations: 1: Institute of Macromolecular Chemistry "P. Poni", 41A Gr. Ghica Voda Alley, Iasi, RO-700487, Romania

Publication date: 2007-01-01