Fabrication and characterization of multi-component organosilane nanofilms
Authors: Takahara A.; Sakata H.; Morita M.; Koga T.; Otsuka H.
Source: Composite Interfaces, Volume 10, Numbers 4-5, 2003 , pp. 489-504(16)
Publisher: VSP, an imprint of Brill
Abstract:
Multi-component micropatterned organosilane monolayers are fabricated on a Si-wafer substrate by stepwise site-specific vacuum ultraviolet (VUV)-ray photodecomposition and chemisorption. The introduction of different organosilane components is confirmed by X-ray photoelectron spectroscopy (XPS). Atomic force microscopic and lateral force microscopic observations reveal that the line-widths of the micropatterned surface correspond to those of the photomask. Contact angle measurement reveals that the micropatterning of the surface functional groups influences the magnitudes of surface free energy. A line pattern with high wetting contrast shows anisotropic water condensing behavior. Also, the patterned surface is used for the site-specific polymerization and site-specific adsorption of microparticles.Keywords: ORGANOSILANE; PHOTODECOMPOSITION; CHEMISORPTION; PATTERNING; SURFACE NANOSTRUCTURE; SURFACE PROPERTIES; MICROPARTICLE; POLYMER ULTRATHIN FILM.
Document Type: Research article
DOI: http://dx.doi.org/10.1163/156855403771953713
Publication date: 2003-08-01
- In this: publication
- By this: publisher
- In this Subject: Chemistry , Engineering/Technology , Materials & Manufacturing
- By this author: Takahara A. ; Sakata H. ; Morita M. ; Koga T. ; Otsuka H.

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