Investigation of Microstructure and V-Defect Formation in InxGa1-xN/GaN MQW Grown Using Temperature-Gradient Metalorganic Chemical Vapor Deposition

Authors: Johnson, M.C.; Liliental-Weber, Z.; Zakharov, D.N.; McCready, D.E.; Jorgenson, R.J.; Wu, J.; Shan, W.; Bourret-Courchesne, E.D.

Source: Journal of Electronic Materials, Volume 34, Number 5, May 2005 , pp. 605-611(7)

Publisher: Minerals, Metals & Materials Society

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Abstract:

Temperature-gradient metalorganic chemical vapor deposition (MOCVD) was used to deposit InxGa1-xN/GaN multiple quantum well (MQW) structures with a concentration gradient of indium across the wafer. These MQW structures were deposited on low defect density (2 × 108 cm-2) GaN template layers for investigation of microstructural properties and V-defect (pinhole) formation. Room temperature (RT) photoluminescence (PL) and photomodulated transmission (PT) were used for optical characterization, which show a systematic decrease in emission energy for a decrease in growth temperature. Triple-axis x-ray diffraction (XRD), scanning electron microscopy, and cross-sectional transmission electron microscopy were used to obtain microstructural properties of different regions across the wafer. Results show that there is a decrease in crystal quality and an increase in V-defect formation with increasing indium concentration. A direct correlation was found between V-defect density and growth temperature due to increased strain and indium segregation for increasing indium concentration.

Keywords: V DEFECTS (PINHOLES); INGAN/GAN; HIGH-RESOLUTION X-RAY DIFFRACTION (XRD); TRANSMISSION ELECTRON MICROSCOPY; METALORGANIC CHEMICAL VAPOR DEPOSITION (MOCVD)

Document Type: Regular paper

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