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Home / Synthetic Communications, Volume 42, Number 24

Acid-Catalyzed Ether Rearrangement: Total Synthesis of Isomimosifoliol and (±)-Dihydromimosifoliol

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Authors: Arava, Veera Reddy 1 ; Malreddy, Sashibhushan 1 ; Thummala, Sreenivasulu Reddy 2 ; 

Source: Synthetic Communications, Volume 42, Number 24, 15 December 2012, pp. 3545-3552(8)

Publisher: Taylor and Francis Ltd

DOI: https://doi.org/10.1080/00397911.2011.567882

An acid-catalyzed rearrangement of benzyl phenyl ethers to diphenylmethane derivatives, followed by salt formation and Hofmann elimination, is a simple method for the syntheses of isomimosifoliol and dihydromimosifoliol.

Keywords: Benzyl phenyl ethers; Hofmann elimination; ether rearrangement; tetraalkylammonium salts

Document Type: Research Article

Affiliations: 1: Research and Development Laboratories, Suven Life Sciences Ltd., Hyderabad, India 2: Department of Chemistry,S. K. University, Anantapur, India

Publication date: 15 December 2012

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