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KF/Al 2 O 3 -Mediated Michael Addition of Thiols to Electron‐Deficient Olefins

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Potassium fluoride supported on alumina efficiently catalyzes Michael addition of aromatic and aliphatic thiols to a variety of conjugated alkenes such as a,ß-unsaturated carbonyl compounds, carboxylic esters, amides, nitriles and chalcones. The Michael adducts are produced in good to excellent yields and relatively in short times. The catalyst can be recycled for subsequent reactions without any appreciable loss of efficiency.
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Keywords: Electron‐deficient olefins; KF/Al 2 O 3; Michael addition; thiols

Document Type: Research Article

Affiliations: Sharif University of Technology, Department of Chemistry, Tehran, Iran

Publication date: 01 January 2005

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