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Preparation and Application of a Novel Functionalized Coconut Coir Pith as a Recyclable Adsorbent for Phosphate Removal

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Abstract:

This study was to develop a new adsorbent, Iron(III) complex of an amino-functionalized polyacrylamide-grafted coconut coir pith (CP), a lignocellulosic residue, for the removal of phosphate from water and wastewater. The kinetics of adsorption follows a pseudo-second-order model. The equilibrium sorption capacity of 96.31 mg/g was determined at 30°C from the Langmuir isotherm equation. Complete removal of 16.4 mg/L phosphate in 1 L of fertilizer industry wastewater was achieved by 1.5 g/L AM-Fe-PGCP at pH 6.0. The acid treatment (0.1 M HCl) and re-introduction of Fe3+ lead to a reactivation of the spent adsorbent and can be reused through many cycles of water treatment and regeneration without any loss in the adsorption capacity.

Keywords: Adsorption isotherm; coir pith; graft copolymerization; phosphate; wastewater

Document Type: Research Article

DOI: http://dx.doi.org/10.1080/01496390903017899

Affiliations: Department of Chemistry, University of Kerala, Kariavattom, Trivandrum, India

Publication date: September 1, 2009

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