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Liquidus Curves of NH 4 NO 3 (aq) Calculated from the Modified Adsorption Isotherm Model for Aqueous Electrolytes

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Abstract:

The Stokes‐Robinson modification of the Brunauer‐Emmett‐Teller (BET) adsorption isotherm is used to calculate the liquidus curve of NaNO 3 (aq) including the eutectic point and metastable phases. The method described here represents a simplified approach to predict the liquidus curves with sparse information and considers the presence of several crystalline solid phases of NH 4 NO 3 .

Keywords: Activity coefficients; Brunauer‐Emmett‐Teller (BET); absorption isotherm; aqueous electrolyte; eutectic

Document Type: Research Article

DOI: http://dx.doi.org/10.1080/01496390600743045

Affiliations: Nuclear Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN, USA

Publication date: January 1, 2006

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