THERMOCHEMISTRY STUDY ON THE EXTRACTION OF Co(II) AND Ni(II) WITH CYANEX 272 IN KEROSENE1 *
The extraction of Co(II) and Ni(II) from sulfate solution with Cyanex 272 in kerosene has been studied by titration microcalorimetry. The heats produced in the reaction processes were determined by the power–time curves and the ? r H ? m values at 298 K were identified. The extraction equilibrium constants and thermodynamic functions at different temperatures were calculated.
Keywords: Co(II); Cyanex 272; Extraction; Microcalorimetry; Ni(II); Reaction heat
Document Type: Research Article
Affiliations: 1: Dept. of Chemistry, Qufu Normal University, Qufu, 273165, China 2: Qingdao Institute of Chem. Tech., Qingdao, 266042, P. R. China
Publication date: 01 January 2001
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