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Triphenylmethanethiol as a Precursor for the Simultaneous Formation of Bis (Triphenylmethyl) Sulfide, Bis(Triphenylmethyl) Trisulfide, and Bis(Triphenylmethyl) Peroxide: Crystal Structures and Hirshfeld Surface Analyses

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Structurally identified, three unexpected products, obtained from the reaction of tritphenylmethanethiol with (+)-R-pulegone, i.e., bis(triphenylmethyl) sulfide, bis(tripheny- lmethyl) trisulfide, and bis(triphenylmethyl) peroxide, have been examined using Hirshfeld surface analysis. This analysis has been also performed for several of their simple

analogues. Comparison of the results obtained shows that relative contributions of close contacts to the Hirshfeld surfaces of the molecules depend on the number of sulfur atoms between the central C atoms of compounds Ph3CSnCPh3 (n = 1, 2, 3 and 6), and in the case of Ph3XO2XPh3 (X = C, Si, Ge) compounds on the type of central X atom.
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Keywords: Hirshfeld surface analysis; fingerprint plots; multiple phenyl embrace

Document Type: Research Article

Affiliations: 1: Jan Dlugosz University in Czestochowa, Institute of Chemistry, Environmental Protection and Biotechnology, Jan Dlugosz University in Czestochowa, Czestochowa, Poland 2: Faculty of Chemistry, Adam Mickiewicz University, Poznan, Poland

Publication date: 01 April 2013

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