Recent Progress in Synthetic and Mechanistic Aspects of Phosphonate C-Radical Chemistry

Authors: Bałczewski, Piotr; Bodzioch, Agnieszka

Source: Phosphorus, Sulfur, and Silicon and the Related Elements, Volume 184, Number 4, April 2009 , pp. 1076-1090(15)

Publisher: Taylor and Francis Ltd

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Abstract:

Progress in radical chemistry of C─C bond formation reactions as well as C-heteroatom (halogen, O, S, Se) and C─C bonds cleavage reactions under reductive conditions, involving phosphonate C-centered radicals, is reviewed with special emphasis on the achievements during the past seven years in iodine atom transfer addition (I-ATRA) and cyclization (I-ATRC) reactions, which were developed in this laboratory.

Keywords: I-ATRA and I-ATRC reactions; phosphonate; radical; radical asymmetric induction; radical C─C and C-heteroatom (halogen, S, Se) bonds scission; radical C─C bond formation

Document Type: Research article

DOI: http://dx.doi.org/10.1080/10426500902737380

Affiliations: 1: Department of Heteroorganic Chemistry, Center of Molecular and Macromolecular Studies, Polish Academy of Sciences, Łodz, Poland

Publication date: 2009-04-01