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Catalytic Conversion of Epoxides to 1,3-Dioxolanes with Phosphomolybdic Acid (PMA) in Solution and under Solvent-Free Conditions

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The fast and efficient conversion of epoxides into 2,2-dimethyl-1,3-dioxolanes was studied with catalytic amounts of phosphomolybdic acid (PMA) (0.1-0.2 mol %) at room temperature in solution and under solvent-free conditions. The products were obtained in high to excellent yields within 1-2 min.

Keywords: 1,3-Dioxolanes; catalytic; epoxides; phosphomolybdic acid; solvent-free

Document Type: Research Article

Affiliations: Department of Chemistry, Faculty of Sciences, Urmia University, Urmia, Iran

Publication date: 01 September 2008

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