Synthese Et Etude Electrochimique De Disulfures Thiopheniques
Unsymmetrical and cyclic disulfides with thiophene units have been prepared. Electrochemical studies show the alteration of their behavior versus thiophene parents due to the second oxydation site. Polymerization of some of them leads to electroactive materials. A new efficient synthesis of the dithieno[3,2-c:2′,3′-e][1,2] dithiine is described.
Keywords: Electrochemistry; disulfure; passivation; polymerization; pyrrole; thiophene
Document Type: Research Article
Affiliations: Laboratoire de Chimie Moléculaire et Thioorganique, ENSI-CAEN, Université de Caen, Caen, France
Publication date: 01 January 2006
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