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Home / Phosphorus, Sulfur, and Silicon and the Related Elements, Volume 179, Numbers 4-5

INORGANIC RINGS WITH GALLIUM ORGANYLS AND IMINODIPHOSPHINECHALCHOGENIDES

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The organometallic complexes of general formula [Me2Ga{(XPR2) (YPR′2)N}] (R, R′=Ph, X, Y=O, (1); R, R′=Ph, X, Y=S (2); R, R′=Ph, X=O, Y=S (3); R=Me, R′=Ph, X=O, Y=S (4)) were obtained by alkane eliminations from Me3Ga and the free acidic ligands, LH, in toluene solutions. Complexes1–4seem to be potential precursors to cationic gallium species.

Keywords: Cations; iminodiphosphinechalchogenides; organogallium complexes

Document Type: Research Article

Affiliations: Universidad Autónoma del Estado de Morelos, Morelos, México

Publication date: 01 April 2004

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