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Natural Polymer Electrolyte System Based on Sago: Structural and Transport Behavior Characteristics

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The development of natural polymer electrolytes (NPEs) based on sago was accomplished in this work by incorporating NH4Br via the solution-casting method. The polymer-salt complex formation and ionic conduction of the NPEs were analyzed by FT-IR and impedance measurement studies. The highest ionic conductivity for the sago-based NPE system at room temperature is 6.90 × 10−9 Scm−1. In addition, the temperature-dependent ionic conductivity of the NPE system obeys the Arrhenius rule. It was shown that the conducting species in this present work is predominantly due to proton (H+), which was confirmed via FT-IR analysis.

Keywords: Ionic conductivity; Polymer electrolytes; Proton (H+); Sago

Document Type: Research Article

Affiliations: Advanced Materials Research Group, Renewable Energy Research Interest Group, Department of Physical Sciences, Faculty of Science and Technology, Universiti Malaysia Terengganu, Kuala Terengganu,Terengganu, Malaysia

Publication date: 01 November 2012

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