Note on the Relation between the Parameters of the Mark-Houwink-Kuhn-Sakurada Equation

Authors: Halabalová, Věra1; Šimek, Lubomír1; Dostál, Jiří1; Bohdanecký, Miloslav2

Source: International Journal of Polymer Analysis and Characterization, Volume 9, Numbers 1-3, Numbers 1-3/January–June 2004 , pp. 65-75(11)

Publisher: Taylor and Francis Ltd

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Abstract:

The relation between the parameters K and a of the equation[η]=KM a , which has been empirically established by several authors, is discussed. Equations describing this relation are derived based on the two-parameter theory of the intrinsic viscosity for flexible chain polymers(where a 0.8). The correspondence of calculated and empirical results is good.

Keywords: Equation [η]=KM a; Interpretation; Parameters K and a

Document Type: Research Article

DOI: http://dx.doi.org/10.1080/10236660490890484

Affiliations: 1: Tomas Bata University, Zlín, Czech Republic 2: Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Prague, Czech Republic

Publication date: January 1, 2004

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