Skip to main content

Kinetics and Mechanism of Oxidation of Mannitol by Sulphato-cerium(IV) Species in Aqueous Acid Medium

Buy Article:

$55.00 plus tax (Refund Policy)

The kinetics of oxidation of mannitol by cerium(IV) in sulphuric acid medium have been studied. The spectral analysis of hydrazone derivative of the product indicates the product to be an aldehyde. The substrate forms an intermediate complex with the oxidant as is observed both kinetically and spectrophotometrically. Ce(SO4)2 has been considered to be the reactive sulphato-cerium(IV) species. The proposed mechanism corresponds to the rate law−d[Ce(IV)]dt=2kK[RCH2OH][Ce(IV)](1+K[RCH2OH])(1+K3[HSO4])where R=CH2OH(CHOH)4. All the rate parameters have been evaluated.
No Reference information available - sign in for access.
No Citation information available - sign in for access.
No Supplementary Data.
No Data/Media
No Metrics

Keywords: Cerium(IV); Kinetics; Mannitol; Oxidation

Document Type: Research Article

Publication date: 2002-01-01

More about this publication?
  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more