STRUCTURE AND PROPERTIES OF EPITAXIAL THIN FILMS OF Bi2FeCrO6: A MULTIFERROIC MATERIAL POSTULATED BY AB-INITIO COMPUTATION

Authors: NECHACHE, R.¹; HARNAGEA, C.¹; CARIGNAN, L.-P.²; MENARD, D.²; PIGNOLET, A.¹

Source: Integrated Ferroelectrics, Volume 101, Number 1, 2008 , pp. 152-163(12)

Publisher: Taylor and Francis Ltd

Abstract:

Experimental results on Bi2FeCrO6 (BFCO) epitaxial films deposited by laser ablation on SrTiO3 substrates are presented. It has been theoretically predicted using first-principles density functional theory that BFCO is ferrimagnetic (with a magnetic moment of 2μB per formula unit) and ferroelectric (with a polarization of ∼ 80 μ C/cm2 at 0K). The crystal structure investigated using X-ray diffraction shows that the films are epitaxial with a high degree of crystallinity. Chemical analysis carried out by X-ray Microanalysis and X-ray Photoelectron Spectroscopy indicates the correct cationic stoichiometry in the BFCO layer, namely (Bi:Fe:Cr = 2:1:1). Cross-section high-resolution transmission electron microscopy images together with selected area electron diffraction confirm the crystalline quality of the epitaxial BFCO films with no identifiable foreign phase or inclusion. The multiferroic character of BFCO is proven by piezoresponse force microscopy (PFM) and magnetic measurements showing that the films exhibit ferroelectric and magnetic hysteresis at room temperature. The local piezoelectric measurements show the presence of ferroelectric domains and their switching at the sub-micron scale.

Keywords: Multiferroics; ferroelectricity; epitaxial thin film; magnetism; piezoresponse

Document Type: Research article

DOI: http://dx.doi.org/10.1080/10584580802470900

Affiliations: 1: INRS Energie, Materiaux et Telecommunications, Varennes, Quebec, Canada 2: Departement de Genie Physique, Ecole Polytechnique de Montreal, Montreal, Quebec, Canada

Publication date: 2008-01-01

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