Supramolecular organization in crystals containing quinoline-2-carboxylates and 9,10-dihydro-9-oxo-10-acridineacetates

Author: Dobrzyńska, Danuta1

Source: Journal of Coordination Chemistry, Volume 59, Number 8, 20 May 2006 , pp. 921-931(11)

Publisher: Taylor and Francis Ltd

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Abstract:

Coordination compounds containing quinoline-2-carboxylate (quin-2-c) or 9,10-dihydro-9-oxo-10-acridineacetate ion (CMA) and ancillary ligands capable of hydrogen bond formation self assemble into 1D, 2D or 3D networks. The system of intermolecular hydrogen bonds that emerges depends mainly on the nature of the ancillary ligand. Aromatic–aromatic and C–H…π interactions are important forces for stabilizing crystal structures. Very strong stacking of aromatic heteropolycycles is found. An overview of complexes with quin-2-c and CMA is given and the organization of their crystal structures discussed.

Keywords: Quinoline-2-carboxylate; 9,10-Dihydro-9-oxo-10-acridineacetate; Crystal structures; Hydrogen bonds; Stacking interactions, C–H…π interactions; Supramolecular chemistry

Document Type: Research article

DOI: 10.1080/00958970500407958

Affiliations: 1: Institute of Inorganic Chemistry and Metallurgy of Rare Elements, Wrocław University of Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland

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