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Evidence of the intercalative redox polymerization of ethylenedioxythiophene into V2O5; achievement of highly conducting poly(3,4-ethylenedioxythiophene)/V2O5 nanohybrids

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We have established a novel method of inserting poly(3,4-ethylenedioxythiophene) (PEDOT) between the layers of V2O5 using a soft process of intercalation. The reaction takes place with the in situ polymerization of EDOT within the framework of crystalline V2O5 with different nominal EDOT/V2O5 ratios. The hybrids PEDOT/V2O5 exhibit a high electrical conductivity.

Keywords: High conductivity; Intercalative redox polymerization; Nano-hybrids

Document Type: Research Article


Affiliations: 1: Centre for Materials for Electronics Technology, Ministry of Communication and Information Technology Government of India Panchawati, Off-Pashan Road Pune 411008 India 2: Institut de Chimie de la Matière Condensée de Bordeaux du CNRS 87 av. A. Schweitzer 33608 Pessac Cedex France 3: Department of Applied Chemistry, College of Natural Sciences Konkuk University Chungju Campus Chungju Chungbuk 380-701 Korea

Publication date: December 1, 2004


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