Authors: Muhandiki, V. S.¹; Shimizu, Y.²; Adou, Y. A. F.³; Matsui, S.⁴

Source: Environmental Technology, Volume 29, Number 3, March 2008 , pp. 351-361(11)

Publisher: Taylor and Francis Ltd

Abstract:

Continuous upflow bench-scale column experiments were carried out to investigate the use of a synthetic form polymer, polypropylene, and polypropylene coated with a thin layer of n-hexane as sorbents for hydrophobic organic compounds present in the effluent of municipal wastewater treatment plant. Two polycyclic aromatic hydrocarbons, namely, phenanthrene and fluorene, were selected as representative hydrophobic organic compounds for experimental purposes. The effect of flow rate, column diameter and column height on the removal efficiency of polycyclic aromatic hydrocarbons was investigated. Removal efficiency was found to correlate well with hydraulic retention time, showing that retention time is the primary parameter in the design of the adsorption column. Dissolved organic matter did not sorb onto polypropylene or polypropylene coated n-hexane, and the presence of dissolved organic matter in the aqueous phase did not significantly affect sorption of polycyclic aromatic hydrocarbons. For experiments with polypropylene coated with n-hexane, an insignificant amount of n-hexane (less than 0.03 times the aqueous solubility of n-hexane in water) was lost due to dissolution in the effluent. The potential use of polypropylene coated n-hexane in upflow column experiments for the removal of hydrophobic organic compounds from the effluent of municipal wastewater treatment plants was demonstrated.

Keywords: n-Hexane; polycyclic aromatic hydrocarbon; polypropylene; sorption; upflow column

Document Type: Research article

DOI: http://dx.doi.org/10.1080/09593330802102330

Affiliations: 1: Department of Environmental Systems Engineering, Ritsumeikan University, Kusatsu, Shiga, 525-8577, Japan 2: Research Center for Environmental Quality Management, Kyoto University, Otsu, Shiga, Japan 3: Department of Civil and Environmental Engineering, University of Pittsburgh, Pittsburgh, USA 4: Emeritus Professor, Kyoto University, Kyoto, Japan

Publication date: 2008-03-01

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