Making sense of lanthanide luminescence

Author: Werts, Martinus H. V.

Source: Science Progress, Volume 88, Number 2, May 2005 , pp. 101-131(31)

Publisher: Science Reviews 2000 Ltd

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Abstract:

The luminescence of trivalent lanthanide ions has found applications in lighting, lasers, optical telecommunications, medical diagnostics, and various other fields. This introductory review presents the basics of organic and inorganic luminescent materials containing lanthanide ions, their applications, and some recent developments. After a brief history of the discovery, purification and early spectroscopic studies of the lanthanides, the radiative and nonradiative transitions of the 4f electrons in lanthanide ions are discussed. Lanthanide-doped phosphors, glasses and crystals as well as luminescent lanthanide complexes with organic ligands receive attention with respect to their preparation and their applications. Finally, two recent developments in the field of luminescent materials are addressed: nearinfrared luminescent lanthanide complexes and lanthanide-doped nanoparticles.

Keywords: lanthanide; luminescence; nanoparticles; photonics

Document Type: Research article

DOI: http://dx.doi.org/10.3184/003685005783238435

Affiliations: 1: Synthèse et Electrosynthèse Organiques, CNRS UMR6510Université de Rennes 1, Campus de Beaulieu, Bât. 10A, F-35042 Rennes Cedex, France

Publication date: 2005-05-15

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