Organic Reactivity in Aot-Stabilized Microemulsions

Authors: Astray, G.; Cid, A.; García-Río, L.; Hervella, P.; Mejuto, J.C.; Pérez-Lorenzo, M.

Source: Progress in Reaction Kinetics and Mechanism, Volume 33, Number 1, 2008 , pp. 81-97(17)

Publisher: Science Reviews 2000 Ltd

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Abstract:

Microemulsions are highly versatile reaction media, which currently find many applications. In this review, we shall describe recent trends in the use of microemulsions as organic reaction media, and present models for their functioning, in particular the pseudophase model. This model allows a quantitative explanation of organic reactivity in these microheterogeneous media.

Keywords: REVERSE MICELLE; MICROEMULSION; AOT; KINETICS; PSEUDOPHASE MODEL; REACTIVITY; WATER POOL; MICRODROPLET

Document Type: Review article

DOI: http://dx.doi.org/10.3184/146867807X273173

Publication date: 2008-03-01

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  • Progress in Reaction Kinetics & Mechanism is an international journal for the quarterly publication of both in-depth reviews and research articles.

    In-depth reviews are comprehensive accounts bringing together work from many sources with the aim of providing an article of lasting value that will become established as the reference source in the particular subject. Research articles, on the other hand, normally focus on a relatively new or recently developed field or technique giving a state-of-the-art account of the subject and may well refer to a narrower range of existing work. It covers the fields of kinetics and mechanisms of chemical processes in the gas phase and solution of both simple and complex systems.

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