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Free Content Nitroso group transfer reactions between N-methyl-N-nitroso-p-toluene sulfonamide and N-alkylamines in CTACl micellar aggregates

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The influence of micellar media upon the transnitrosation reaction between N-methyl-N-nitroso-p-toluensulfonamide (MNTS) and three linear alkylamines (n-octylamine (OA), N-methyl-n-octylamine (MOA) and N,N-dimethyl-n-octylamine (DMOA)) in micelles of Cetyltrimethylammonium Chloride (CTACl) has been studied. The rate constants were obtained and the pseudophase model allowed us to obtain the intrinsic reactivity constants in the aqueous pseudophase and in the micellar pseudophase (k2 i and k2 w) and the binding constant of the amines to the micellar phase (Ka).
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Document Type: Research Article

Affiliations: Departamento de Química Física, Facultade de Química, Universidade de Santiago de Compostela, 15782, Santiago de Compostela, Spain

Publication date: 2006-04-30

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  • Progress in Reaction Kinetics & Mechanism is an international journal for the quarterly publication of both in-depth reviews and research articles.

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