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Free Content Nitroso group transfer reactions between N-methyl-N-nitroso-p-toluene sulfonamide and N-alkylamines in CTACl micellar aggregates

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The influence of micellar media upon the transnitrosation reaction between N-methyl-N-nitroso-p-toluensulfonamide (MNTS) and three linear alkylamines (n-octylamine (OA), N-methyl-n-octylamine (MOA) and N,N-dimethyl-n-octylamine (DMOA)) in micelles of Cetyltrimethylammonium Chloride (CTACl) has been studied. The rate constants were obtained and the pseudophase model allowed us to obtain the intrinsic reactivity constants in the aqueous pseudophase and in the micellar pseudophase (k2 i and k2 w) and the binding constant of the amines to the micellar phase (Ka).
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Document Type: Research Article

Affiliations: Departamento de Química Física, Facultade de Química, Universidade de Santiago de Compostela, 15782, Santiago de Compostela, Spain

Publication date: 30 April 2006

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  • Progress in Reaction Kinetics & Mechanism is an international journal for the quarterly publication of both in-depth reviews and research articles.

    In-depth reviews are comprehensive accounts bringing together work from many sources with the aim of providing an article of lasting value that will become established as the reference source in the particular subject. Research articles, on the other hand, normally focus on a relatively new or recently developed field or technique giving a state-of-the-art account of the subject and may well refer to a narrower range of existing work. It covers the fields of kinetics and mechanisms of chemical processes in the gas phase and solution of both simple and complex systems.

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