Ytterbium (III) triflate catalysed [3 + 2] cycloaddition involving isothiocyanates and epichlorohydrin
Authors: Xie, Yuanyuan; Chen, Xiaodong; Su, Weike
Source: Journal of Chemical Research, Volume 2009, Number 2, February 2009 , pp. 129-132(4)
Publisher: Science Reviews 2000 Ltd
Abstract:
Highly regioselective cycloadditions occur in reactions of substituted isothiocyanates and epichlorohydrin to give N-(5-(chloromethyl)-1,3-oxathiolan-2-ylidene)anilines catalysed by Yb(OTf)3. The configuration is retained at the chiral centres of the epoxides.Keywords: ISOTHIOCYANATE; EPICHLOROHYDRIN; YTTERBIUM TRIFLATE
Document Type: Research article
DOI: http://dx.doi.org/10.3184/030823409X401952
Publication date: 2009-02-01
- The Journal of Chemical Research is a monthly journal which has a broad international authorship and publishes research papers and reviews in all branches of experimental chemistry.
Recent papers have described new synthetic methods, new heterocyclic compounds, new natural products, and the inorganic chemistry of metal complexes. Now in its 34th year, the Journal of Chemical Research was established in 1977 as a joint venture by the British, French and German chemical societies and maintains the high standards set by the founding societies. Each paper is independently peer reviewed and only carefully evaluated contributions are accepted.
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- In this Subject: Chemistry (General) , Organic Chemistry , Physical & Theoretical Chemistry
- By this author: Xie, Yuanyuan ; Chen, Xiaodong ; Su, Weike

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