The effective preparation of secondary amines bearing a vinylsilane functionality via the reaction of primary amines with α-chlorine-substituted allylsilanes catalysed by CuCl

Authors: Kozuka, Makoto; Mitani, Michiharu

Source: Journal of Chemical Research, Volume 2007, Number 8, August 2007 , pp. 464-467(4)

Publisher: Science Reviews 2000 Ltd

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Abstract:

The reaction of α-chlorine-substituted allylsilanes with primary amines was promoted by CuCl to result in the selective formation of secondary amines bearing the vinylsilane functionality by a probable SN2`-allylation keeping the silyl group intact.

Keywords: VINYLSILANE, ALLYLSILANE, COPPER CATALYST, SECONDA

Document Type: Research article

DOI: 10.3184/030823407X237795

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