The effective preparation of secondary amines bearing a vinylsilane functionality via the reaction of primary amines with α-chlorine-substituted allylsilanes catalysed by CuCl

Authors: Kozuka, Makoto; Mitani, Michiharu

Source: Journal of Chemical Research, Volume 2007, Number 8, August 2007 , pp. 464-467(4)

Publisher: Science Reviews 2000 Ltd

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Abstract:

The reaction of α-chlorine-substituted allylsilanes with primary amines was promoted by CuCl to result in the selective formation of secondary amines bearing the vinylsilane functionality by a probable SN2`-allylation keeping the silyl group intact.

Keywords: VINYLSILANE, ALLYLSILANE, COPPER CATALYST, SECONDA

Document Type: Research article

DOI: http://dx.doi.org/10.3184/030823407X237795

Publication date: 2007-08-01

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The Journal of Chemical Research is a monthly journal which has a broad international authorship and publishes research papers and reviews in all branches of experimental chemistry.
Recent papers have described new synthetic methods, new heterocyclic compounds, new natural products, and the inorganic chemistry of metal complexes. Now in its 34th year, the Journal of Chemical Research was established in 1977 as a joint venture by the British, French and German chemical societies and maintains the high standards set by the founding societies. Each paper is independently peer reviewed and only carefully evaluated contributions are accepted.
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