Reaction between 5-benzylidene-2,2-dimethyl-1,3-dioxane-4,6-dione and tert-butyl isocyanide in the presence of ethane-1,2-diol or catechol
Authors: Yavari, Issa; Yavari, Issa; Zare, Hasan; Zare, Hasan; Mohtat, Bita; Mohtat, Bita
Source: Journal of Chemical Research, Volume 2007, Number 3, March 2007 , pp. 152-154(3)
Publisher: Science Reviews 2000 Ltd
Abstract:tert-Butyl isocyanide undergoes a smooth reaction with 5-benzylidene-2,2-dimethyl-1,3-dioxane-4,6-diones (benzylidene Meldrum‘s acids) in the presence of ethane-1,2-diol or catechol to produce functionalised N-tert-butyl-2-(5,7-dioxo-1,4-dioxepane-6-yl)-2-aryl-ethanamides or bis-(2-hydroxyphenyl) 2-[2-(tert-butylamino)-1-aryl-2-oxoethyl]-malonates in good yields.
Document Type: Research Article
Publication date: March 2007
The Journal of Chemical Research is a monthly journal which has a broad international authorship and publishes research papers and reviews in all branches of experimental chemistry.
Established in 1977 as a joint venture by the British, French and German chemical societies it maintains the high standards set by the founding societies. Each paper is independently peer reviewed and only carefully evaluated contributions are accepted.
Recent papers have described new synthetic methods, new heterocyclic compounds, new natural products, and the inorganic chemistry of metal complexes.
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