The mild synthesis of oxime phosphates by Atherton-Todd reaction

Authors: Ming Shu Wu,; Xiang Zhu Zhang,

Source: Journal of Chemical Research, Volume 2007, Number 3, March 2007 , pp. 146-147(2)

Publisher: Science Reviews 2000 Ltd

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Abstract:

The oximes (1a-i) on reaction with diethyl phosphonates (2) in the presence of triethylamine using chlorocarbons as solvents mildly provide oxime phosphates (3a-i) in good yields and have no the Beckmann rearrangement.

Keywords: OXIME PHOSPHATES, ATHERTON-TODD REACTION

Document Type: Research article

DOI: http://dx.doi.org/10.3184/030823407X196944

Publication date: 2007-03-01

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  • The Journal of Chemical Research is a monthly journal which has a broad international authorship and publishes research papers and reviews in all branches of experimental chemistry.

    Recent papers have described new synthetic methods, new heterocyclic compounds, new natural products, and the inorganic chemistry of metal complexes. Now in its 34th year, the Journal of Chemical Research was established in 1977 as a joint venture by the British, French and German chemical societies and maintains the high standards set by the founding societies. Each paper is independently peer reviewed and only carefully evaluated contributions are accepted.

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