Stereospecific synthesis of bisdihydroxylated dicyclopentadiene

Authors: Salamci, Emine; Sahin, Ertan

Source: Journal of Chemical Research, Volume 2007, Number 1, January 2007 , pp. 62-64(3)

Publisher: Science Reviews 2000 Ltd

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Abstract:

The first bisdihydroxylation of dicyclopentadiene (3) with OsO4-NMO gave the exo-tetrol 4a as a sole product in one step. The stereoselectivity in bisdihydroxylation of 3 has been determined by an X-ray diffraction analysis of the compound 4a and tetraacetate 4b.

Keywords: CYCLITOLS, CRYSTAL STRUCTURE, BISDIHYDROXYLATION,

Document Type: Research article

DOI: http://dx.doi.org/10.3184/030823407780199487

Publication date: 2007-01-01

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  • The Journal of Chemical Research is a monthly journal which has a broad international authorship and publishes research papers and reviews in all branches of experimental chemistry.

    Recent papers have described new synthetic methods, new heterocyclic compounds, new natural products, and the inorganic chemistry of metal complexes. Now in its 34th year, the Journal of Chemical Research was established in 1977 as a joint venture by the British, French and German chemical societies and maintains the high standards set by the founding societies. Each paper is independently peer reviewed and only carefully evaluated contributions are accepted.

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