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Free Content A novel one pot synthesis of benzyl sulfides: samarium-induced, benzyl bromide mediated reduction of alkyl thiocyanates and diaryl disulfides in methanol

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Abstract:

A convenient synthesis of benzyl sulfides by the treatment of alkyl thiocyanates or diaryl disulfides with metallic samarium and benzyl bromide in methanol has been developed.

Keywords: METALLIC SAMARIUM, BENZYL BROMIDE, BENZYL SULFIDES, ALKYL THIOCYANATES, DIARYL DISULFIDES

Document Type: Research Article

DOI: http://dx.doi.org/10.3184/030823406777980628

Publication date: July 1, 2006

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  • The Journal of Chemical Research is a monthly journal which has a broad international authorship and publishes research papers and reviews in all branches of experimental chemistry.

    Established in 1977 as a joint venture by the British, French and German chemical societies it maintains the high standards set by the founding societies. Each paper is independently peer reviewed and only carefully evaluated contributions are accepted.

    Recent papers have described new synthetic methods, new heterocyclic compounds, new natural products, and the inorganic chemistry of metal complexes.

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