Synthesis and crystal structure of the chiral-linked tetrahedral cluster [(μ3-Se)RuCo2(CO)8]2 (DIOP)

Authors: Zhu, Bao-Hua; Hong, Hong; Yin, Yuan-Qi; Sun, Jie

Source: Journal of Chemical Research, Volume 2004, Number 11, November 2004 , pp. 756-757(2)

Publisher: Science Reviews 2000 Ltd

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Abstract:

The new chiral Ru-Co mixed-metal linked tetrahedral cluster [(μ3-Se)RuCo2(CO)8]2(DIOP) 3 has been synthesised from reaction between (μ3-Se)RuCo2(CO)9 1 and the (-)-DIOP [ 2 (2,2-dimethyl-1,3-dioxolane-4,5-diylbis-methylene) bisdiphenylphosphine] diphosphine compound. The structure of cluster 3 has been established by single-crystal X-ray diffraction method.

Keywords: CHIRAL, RU-CO CLUSTER, TETRAHEDRAL, DIOP, X-RAY

Document Type: Research article

DOI: http://dx.doi.org/10.3184/0308234043431492

Publication date: 2004-11-01

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