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Free Content Microwave accelerated synthesis of cyclopentadienyl bis-phosphine ruthenium (II) thiolato complexes using focused microwave irradiation

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The synthesis of cyclopentadienyl bis-phosphine ruthenium thiolato complexes of the type [RuCp(dppm)SR] from [RuCp(PPh3)2 Cl] using conventional heating and microwave irradiation using a focused monomode reactor is described and the protocols compared. A considerable decrease of the reaction time is observed under microwave conditions. Yields by both methods are comparable. Functionalities such as esters, carboxylic acids and amides on the thiolato ligands are tolerated under the reaction conditions.
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Keywords: CYCLOPENTADIENYL BIS PHOSPINE RUTHENIUM (II) THIOLATO COMPLEXES

Document Type: Research Article

Publication date: 2002-02-01

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  • The Journal of Chemical Research is a monthly journal which has a broad international authorship and publishes research papers and reviews in all branches of experimental chemistry.

    Established in 1977 as a joint venture by the British, French and German chemical societies it maintains the high standards set by the founding societies. Each paper is independently peer reviewed and only carefully evaluated contributions are accepted.

    Recent papers have described new synthetic methods, new heterocyclic compounds, new natural products, and the inorganic chemistry of metal complexes.

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