Spectral Characteristics of Ba2B2P2O10:Eu3+ Phosphor
Ba2B2P2O10:Eu3+ phosphor was synthesized by high temperature solid-state method. BaCO3(A.R.), NH4H2PO4(A.R), H3BO3(A.R.), Eu2O3(99.99%), NH4Cl(A.R.), Li2CO3(A.R.), Na2CO3(A.R.) and K2CO3(A.R.) were used for starting materials. After these individual materials were blended and grounded thoroughly in an agate mortar, the homogeneous mixture was heated at 1 000 for 3 h, and the phosphors were obtained. The phase present of the samples were characterized by powder X-ray diffraction (XRD) (D/max-rA, Cu Kα, 40 kV, 40 mA, λ=0.154 06 nm). The spectral characteristics of these phosphors were measured by a SHIMADZU RF-540 fluorescence spectrophotometer. Under the condition of 400 nm excitation, the emission spectrum of Ba2B2P2O10:Eu3+ phosphor shows several bands at 600, 618, 627 and 660 nm respectively, which correspond to the electric dipole 5 D 0→7 F 1, 7 F 2, 7 F 3 and 7 F 4 transitions of Eu3+. The effect of Eu3+ concentration or charge compensator on the emission intensity of Ba2B2P2O10:Eu3+ phosphor was investigated, and the result shows that the emission intensity of the phosphor increases with increasing Eu3+ concentration, viz. the concentration quenching has not existed. And the emission intensity of the phosphor was enhanced by doping charge compensator. All the results illuminate that Ba2B2P2O10:Eu3+ phosphor is a promising red phosphor for white LEDs.
No Reference information available - sign in for access.
No Citation information available - sign in for access.
No Supplementary Data.
No Article Media
Document Type: Research Article
Publication date: 01 August 2010
More about this publication?
- Spectroscopy and Spectral Analysis, founded in 1981, is sponsored by the Chinese Central Iron & Steel Research Institute. "Spectroscopy and Spectral Analysis" has been indexed in SCI(1999), Ei(1992), MEDLINE(1999), and AJ (1999). "Spectroscopy and Spectral Analysis" publishes original contributions on various fields in Spectroscopy, including research results on laser spectroscopy, IR, Ramn, UV/Vis, Optical Emission, Absorption and Fluorescence spectroscopy, X-ray Fluorescence, and Spectrochemical Analysis, as well as Reseach paper, Research notes, Experimental Technique and Instrument, Review and Progress on the latest development of spectroscopy and spectrochemical anlysis, etc. "Spectroscopy and Spectral Analysis" is published monthly by Peking University Press with book sizes of large 16-mo format , and 292 pages per issue.
- Editorial Board
- Submit a Paper
- Ingenta Connect is not responsible for the content or availability of external websites