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Polymers from Biobased-Monomers: Macroporous Itaconic Xerogels Prepared in Deep Eutectic Solvents

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New methods of preparation of crosslinked polymers from itaconic acid as a renewable monomer have been explored. Synthesis of hydrogels and xerogels from the acid in deep eutectic solvents (DESs) are described and some basic properties of the materials are reported. Most importantly, a surfactant-free method of creation of macroporous poly(itaconic-co-bisacrylamide) by phase separation polymerization in binary mixture of the DES and poly(ethylene glycol) is demonstrated.
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Keywords: CHOLINE CHLORIDE; FREE-RADICAL POLYMERIZATION-CROSSLINKING; HYDROGELS; PHASE SEGREGATION; RENEWABLE MONOMERS

Document Type: Research Article

Publication date: 13 February 2016

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