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Carbon-13 Cross-Polarization Magic-Angle-Spinning Nuclear Magnetic Resonance Investigation of the Interactions Between Maleic Anhydride Grafted Polypropylene and Wood Polymers

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Abstract:

The chemical interactions between maleic anhydride grafted polypropylene (MAPP) and wood were studied with solid-state carbon-13 cross-polarization magic-angle-spinning nuclear magnetic resonance (13C CPMAS NMR) spectroscopy. MAPP was synthesized with 100% 13C enrichment at the C1 and C4 carbons to allow detection of the [1,4-13C2]MAPP functional groups and was melt blended with cellulose, lignin, and maple wood. In the cellulose/MAPP blend, changes in 13C CPMAS NMR corrected signal intensities for the anhydride and dicarboxylic maleic acid functionalities suggested that esterification may have occurred predominantly from the more numerous diacid carbons. A single proton longitudinal relaxation in the rotating frame, HT, for the MAPP and the cellulose carbons in the blend suggested that they were spin coupled, i.e., homogeneous on a 10–200 Angstrom scale. Esterification was also suggested in the lignin/MAPP blend. Furthermore, the more significant changes in the intensities of the carbonyl signals and HT values suggested that lignin may be more reactive to MAPP than cellulose. Finally, when maple was melt blended with MAPP, the same trends in the 13C CP-MAS NMR spectra and HT behavior were observed as when MAPP was blended with cellulose or lignin. This study therefore clarifies that during melt compounding of wood with MAPP, esterification occurs with wood polymers, preferentially with lignin. Understanding the interactions of MAPP with wood is of significance for the development of natural-fiber-reinforced thermoplastic composites.

Keywords: COUPLING MECHANISM; CP-MAS NMR; CROSSED-POLARIZATION MAGIC ANGLE SPINNING; MALEIC ANHYDRIDE GRAFTED POLYPROPYLENE; NUCLEAR MAGNETIC RESONANCE; [1,4-13 C2]MAPP

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/000370208784344442

Affiliations: Washington State University, Department of Civil and Environmental Engineering, Wood Materials and Engineering Laboratory, PO Box 641806, Pullman, Washington 99164-1806

Publication date: May 1, 2008

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