Near-Infrared Analysis of Ground Barley for Use as a Feedstock for Fuel Ethanol Production
The objective of this study was to explore the potential of near-infrared spectroscopy for determining the compositional quality properties of barley as a feedstock for fuel ethanol production and to compare the prediction accuracy between calibration models obtained using a Fourier
transform near-infrared system (FT-NIR) and a dispersive near-infrared system. The total sample set contained 206 samples of three types of barley, hull-less, malt, and hulled varieties, which were grown at various locations in the eastern U.S. from 2002 to 2005 years. A new hull-less barley
variety, Doyce, which was specially bred for potential use in ethanol production, was included in the sample set. One hundred and thirty-eight barley samples were used for calibration and sixty-eight were used for validation. Ground barley samples were scanned on both a FTNIR spectrometer
(10 000 to 4000 cm−1 at 4 cm−1 resolution) and a dispersive NIR spectrometer (400 to 2498 nm at 10 nm resolution), respectively. Six grain components, moisture, starch, β-glucan, protein, oil, and ash content, were analyzed as parameters of barley quality.
Principal component analysis showed that barley samples could be classified by their types: hull-less, malt, and hulled. Partial least squares regression indicated that both FT-NIR and dispersive NIR spectroscopy have the potential to determine quality properties of barley with an acceptable
accuracy, except for β-glucan content. There was no predictive advantage in using a high-resolution FT-NIR instrument over a dispersive system for most components of barley.
FOURIER TRANSFORM NEAR-INFRARED SPECTROSCOPY;
PARTIAL LEAST SQUARES;
Document Type: Research Article
Richard B. Russell Agricultural Research Center, ARS, USDA, P.O. Box 5677, Athens, Georgia 30605
Dept. of Crop & Soil Env. Sciences, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061
Eastern Regional Research Center, ARS, USDA, 600 E. Mermaid Lane, Wyndmoor, Pennsylvania 19038
Publication date: November 1, 2007
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