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Analysis of Phthalate Ester Content in Poly(vinyl chloride) Plastics by Means of Fourier Transform Raman Spectroscopy

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Abstract:

Fourier transform (FT) Raman spectroscopy is applied to a range of phthalate ester plasticizers in pure form as well as in poly(vinyl chloride) (PVC) samples. It is found that phthalate esters as a group can be identified by a set of six characteristic Raman bands. FT-Raman spectra of 22 phthalate esters are given. It is demonstrated that the presence of phthalate esters in PVC products is readily detectable by FT-Raman spectroscopy. By use of proper reference samples quantitative determination of the phthalate ester content becomes possible as well.

Keywords: FOURIER TRANSFORM RAMAN; PHTHALATE; POLY VINYL CHLORIDE; PVC; QUANTITATIVE RAMAN; SPECTROSCOPY

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/000370204773580248

Affiliations: Department of Chemistry, The Technical University of Denmark, Kemitorvet, B. 207, DK.2800 Lyngby, Denmark

Publication date: April 1, 2004

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