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Raman Spectroscopic Studies of the Thermal Decomposition of Molybdenum Oxide/2,2'-Bipyridine Compounds

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Abstract:

The thermal decompositions of [MoO3(2,2'-bipy)], [Mo2O6(2,2'-bipy)], and [Mo3O9(2,2'-bipy)2] have been studied by Raman spectroscopy. Upon heating, [MoO3(2,2'-bipy)] loses 2,2'-bipyridine and converts to MoO3 through a stable intermediate, [Mo2O6(2,2'-bipy)], whereas [Mo3O9(2,2'-bipy)2] loses 2,2'-bipyridine and transforms to MoO3directly. Vibrational assignments for [MoO3(2,2'-bipy)], [Mo2O6(2,2'-bipy)], and [Mo3O9(2,2'-bipy)2] are proposed.

Keywords: BIPYRIDINE; MOLYBDENUM OXIDE; RAMAN SPECTROSCOPY

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702991947856

Publication date: September 1, 1999

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