@article {Centeno:1999:0003-7028:800,
	author = "Centeno, Miguel Angel and Carrizosa, Ignacio and Odriozola, Jose Antonio",
	title = "Application of Temperature-Programmed Diffuse Reflectance Infrared Fourier Transform Spectroscopy to the Study of the Thermal Evolution of the Species Present in a Reacted Selective Catalytic Reduction V2O5/TiO2 Catalyst",
	journal = "Applied Spectroscopy",
	volume = "53",
	number = "7",
	year = "1999",
	abstract = "Temperature-programmed diffuse reflectance infrared Fourier transform spectroscopy (TPDRIFTS) has been used to characterize a reacted selective catalytic reduction (SCR) vanadia/titania catalyst. At room temperature the reacted catalyst presents ammonium ions adsorbed on the surface. On heating under N2 flow, a surface redox reaction takes place; ammonium ions are oxidized to bridged nitrosyls species, while V5+=O groups are reduced to V3+. Reduction of V5+ species to V3+ ions occurs at lower temperatures than those observed in conventional TPR processes under H2 atmospheres. At higher temperatures, bridged nitrosyls species become monoden-tate, first in an angular configuration and then in a linear one. Previous data on the SCR reaction let us propose that they are desorbed from the surface as gaseous N2O.",
	pages = "800-804",
	url = "http://www.ingentaconnect.com/content/sas/sas/1999/00000053/00000007/art00010",
	doi = "doi:10.1366/0003702991947351",
	keyword = "TEMPERATURE-PROGRAMMED DIFFUSE REFLECTANCE INFRARE, VANADIATITANIA CATALYSTS, SCR REACTED CATALYSTS"
}