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EPR Spectroscopy of Adsorbed Nitroxides to Investigate Catalyst Surfaces

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Abstract:

The use of electron paramagnetic resonance (EPR) for the investigation of catalytic surfaces by means of adsorbed nitroxides is discussed. The possibilities of the paramagnetic probe method in terms of qualitative and quantitative control of the acidity of the catalyst surfaces is demonstrated. Models of the acid site structures in accordance with EPR data are presented.

Keywords: Adsorption sites; Alumina; EPR; Nitroxide; Paramagnetic probe; Silica; Supported catalysts; Zeolites

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702963904700

Affiliations: Department of Chemistry, Moscow State University, Vorobyovy Hills, Moscow, 119899, Russian Federation

Publication date: November 1, 1996

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