Skip to main content

Highly Sensitive Detection System Composed of a Thin, Long, Flow-Through Cell and a Semiconductor Laser for FIA Spectrophotometry and Its Application to the Determination of Total Phosphorus in Water

Buy Article:

$29.00 plus tax (Refund Policy)


A highly sensitive detection system, which was composed of a thin, long, flow-through cell (TLFTC) and a semiconductor laser (SCL), for flow injection analysis (FIA) spectrophotometry has been developed. The new detection system was mainly composed of a thin, long, light path (100 mm x 1.4 mm i.d.), which was made of a polytetrafluoroethylene rod as an absorption cell, along with a GaAIAs semiconductor laser emitting at 780 nm (5 mW) as a light source. With the use of the detection system, the detection sensitivity was improved by about 10 times in comparison to FIA spectrophotometry with a normal flow cell. The detection system can be useful for determinations of many trace components in samples. The determination of total phosphorus in water, with the use of molybdenum-blue photometry, was one of its applications, and the relative standard deviation, detection limit (3σ), and linear range were 1.0%, 0.6, and 1.0-50 μg P/L, respectively. The determined results for the total phosphorus in the water samples by this method were almost coincident with those obtained by the official method. The detection system may also be useful for other flow-based analytical techniques such as liquid chromatography.

Keywords: Eutrophication; FIA spectrophotometry; Semiconductor laser; Thin, long, flow-through cell; Total phosphorus; Water

Document Type: Research Article


Affiliations: 1: Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow G1 1XL, U.K.; present address: Dept. of Environmental Protection, Suzhow Institute of Urban Construction and Environmental Protection, Postcode 215008, Suzhou, Jiangsu, P.R. China 2: Faculty of Integrated Arts and Sciences, University of Tokushima, 1-1, Minami-josanjima-cho, Tokushima 770, Japan

Publication date: September 1, 1996

More about this publication?

Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
Cookie Policy
Cookie Policy
ingentaconnect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more