If you are experiencing problems downloading PDF or HTML fulltext, our helpdesk recommend clearing your browser cache and trying again. If you need help in clearing your cache, please click here . Still need help? Email help@ingentaconnect.com

Compact Raman Spectrometers: Data Handling Methods

$29.00 plus tax (Refund Policy)

Buy Article:

Abstract:

Measurements have been made on a compact dispersive Raman spectrometer of the type often proposed for on-line measurements. Quantitative use of the details of spectra that are produced by this system require different data treatments than those which have been described for longer-focal-length instruments. The data sets are sparsely sampled, and they cover a wide spectral window. Owing to sparse sampling, spectra as recorded have the appearance of piecewise linear approximations. It is necessary to interpolate additional data points in order to observe details of peaks, such as exact positions of maxima. With wider spectral windows, procedures for calibration of the wavenumber axis which have been previously described do not meet our performance criterion: an accuracy of 0.1 cm-1 or better. A model that involves a fifth-order polynomial is needed. On the basis of the performance of this model, atomic lines which give satisfactory results when used as wavenumber references have been identified. Details of a self-modeling procedure for removal of broad-band spectral interferences are described, and its performance is demonstrated.

Keywords: Compact Raman spectrometer; Fluorescence removal from Raman spectra; Wavenumber axis calibration for Raman spectrometers

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702963905222

Affiliations: Department of Chemistry, Florida State University, Tallahassee, Florida 32306-3006

Publication date: August 1, 1996

More about this publication?
Related content

Tools

Favourites

Share Content

Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
Cookie Policy
X
Cookie Policy
ingentaconnect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more