Skip to main content

Investigation of Vapor Condensation in Graphite Furnace Atomic Absorption Spectrometry by the Shadow Spectral Digital Imaging Technique

Buy Article:

$29.00 plus tax (Refund Policy)


Condensation of vapors of gold (analyte) and matrices of various chemical modifiers and compounds in graphite furnace atomic absorption spectrometry was investigated by using the shadow spectral digital imaging technique with a charge-coupled device camera. Spatial and temporal nonuniformity in the light scattering was observed, and these effects were attributed to the formation of condensed-phase particles during the processes of high-temperature vaporization and atomization. The materials investigated were Au, MgCl2, NaCl, (NH4)2HPO4, La(NO3)3, and a mixture Pd and Mg(NO3)2. The nonuniform distributions of the condensed-phase particle clouds were attributed to the gas-flow patterns that developed in the graphite tube furnace during heating, as well as the steep temperature gradients that developed along the longitudinal axis of the end-heated graphite tube of the Massmann-type graphite furnace. Differences observed with fast and slow rates of heating were related to thermal expansion of gas and diffusion effects. Use of either a graphite platform or a low argon purge gas flow during the high-temperature heating of the graphite furnace was found to reduce condensation of matrix vapor and to improve accuracy of continuum source background correction.

Keywords: Charge-coupled device camera; Condensation; Graphite furnace; Light-scattering; Shadow spectral digital imaging; Vaporization

Document Type: Research Article


Affiliations: 1: Ottawa-Carleton Chemistry Institute, Department of Chemistry, Carleton University, Ottawa, Ontario K1S 5B6, Canada 2: Institute for Environmental Chemistry, National Research Council of Canada, Ottawa, Ontario K1A 0R9, Canada 3: Geological Survey of Canada, 601 Booth St., Ottawa, Ontario K1A 0E8, Canada

Publication date: June 1, 1996

More about this publication?

Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
Cookie Policy
Cookie Policy
ingentaconnect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more